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Making Graphite Work

• April 26, 2009
• 18:11

  On Break

   » ‎ Making Graphite Work
  As I’m sure regular visitors have noticed, things haven’t been too exciting around here for a while. In lieu of boring you with all the gory details, I’ll just say that MGW is going on a little “break” for the time being. Regular posting should resume sometime in the summer. Until then, enjoy this. LSD [...]
• March 28, 2009
• 22:44

  WNPS Solution

   » ‎ Making Graphite Work
  The chemistry world can be a very small place. Last semester, for example, I TA’ed for a professor who had my undergrad organic professor as her organic TA in undergrad. What does this have to do with Wednesday’s problem? To put it plainly, I don’t remember ever learning oxymercuration from the aforementioned prof. In all [...]
• March 25, 2009
• 20:36

  WNPS: How I Learned to Stop Worrying and Love Carbocations

   » ‎ Making Graphite Work
  Tonight’s problem comes once again from Harvard’s challenging organic problems website. In the early 1980’s, Robert Stevens’s group at UCLA studied nucleophilic additions to and reductions of tetrahydropyridiniums, which could potentially yield alkaloid products. Actually getting to these cyclic imines and iminium ions in the first place can be an interesting exercise in arrow-pushing. It certainly [...]
• March 23, 2009
• 22:43

  From the Lab to the Court

   » ‎ Making Graphite Work
  As an avid Kentucky basketball fan, I guess it’s about time for me to weigh in on this year’s season. What better time than after a spectacular win against a solid Creighton club (that jumped on all of our idiotic mistakes)? Ironically, we have more wins right now than we would have had if we’d made [...]
• March 21, 2009
• 21:47

  WNPS Solution

   » ‎ Making Graphite Work
  Wednesday night’s problem featured a variant of the venerable Staudinger reaction, which can be used to reduce azides to amines or generate iminophosphoranes which can participate in aza-Wittig reactions, which form imines rather than alkenes. The reactivity of azides is apparently more subtle than one might think, if this reaction has anything to say about [...]